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I had the same issue. This is not a Samsung issue, its a Big Sur issue. The first time you are to install the software it prompts you to go to System Preferences > Security & Privacy and under the General tab you are to find a Notification under the "Allow apps downloaded from:" section. If you miss that at the first installation it will never appear again unless you switch macOs in recovery mode and disable kernel extensions blocking. Unistall the Samsung Portable SSD utility using the script inside the Application contents. Follow the guidelines in the medium article to disable the feature mentioned above. Then reinstall the Samsung Portable SSD utility and you will get the notification saying the extension has been blocked. Click on go to Security & Privacy settings and under The General tab you will see the text I described earlier. Unlock the settings and click on details. Tick on Samsung Electronics close the details window and restart your Mac as prompted. Then, remove your Samsung Portable SSD and open the Samsung Portable SSD utility. Connect your SSD press refresh and you should be fine. Lastly, reboot to recovery mode and enable the kernel extensions blocking feature.
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